| Name | Population | Latitude/Longitude |
| 1 | Kiev, Kiev Oblast |
2,514,227 |
50.433 / 30.517 |
| 2 | Kharkiv, Kharkivs'ka Oblast' |
1,430,885 |
50 / 36.25 |
| 3 | Dnipropetrovs'k, Dnipropetrovs'ka Oblast' |
1,032,822 |
48.45 / 34.983 |
| 4 | Donets'k, Donets'ka Oblast' |
1,024,700 |
48 / 37.8 |
| 5 | Odesa, Odessa Oblast |
1,001,558 |
46.477 / 30.733 |
| 6 | Zaporizhzhya, Zaporiz'ka Oblast' |
796,217 |
47.817 / 35.183 |
| 7 | L'viv, L'vivs'ka Oblast' |
717,803 |
49.838 / 24.023 |
| 8 | Kryvyy Rih, Dnipropetrovs'ka Oblast' |
652,380 |
47.917 / 33.35 |
| 9 | Mykolayiv, Mykolayivs'ka Oblast' |
510,840 |
46.967 / 32 |
| 10 | Mariupol', Donets'ka Oblast' |
481,626 |
47.067 / 37.5 |